Ferrocene Ligands

The following is a list of commercially available ferrocene based ligands and catalysts, with links to suppliers. These are listed by ligand/catalyst type as:

P-N

[Phosferrox][PPFA]*

P-S

[FeSulPhos]

1,1′-PP

[CTH-JAFAPhos][Mandyphos][Chenphos]*

[Trifer][Ferrocelane][FerroTANE]*

1,2-PP

[BoPhoz][Josiphos] [JoSPOphos]

[Walphos] [Taniaphos]

Other

C5Ph5-DMAP

 *Reviews available

P-N Ligands and Catalysts

Phosferrox

C28H28FeNOP – PN-L1a [Review available]

C28H28FeNOP_1

Aldrich (S,Sp) (R,Rp)

Strem (S,Sp)(R,Rp)*

TCI (S,Sp)

[*Suppliers drawn structure does not correspond to configuration given]

 

C29H30FeNOP – PN-L1b [Review available]

C29H30FeNOP_1

Aldrich (S,Sp) (R,Rp)

 

C46H43Cl2FeNOP2Ru – [(S,Sp)-PN-L1a]RuCl2(PPh3) [Review available]

C46H43Cl2FeNOP2Ru_1

Aldrich (S,Sp) (R,Rp)

Strem (S,Sp) (R,Rp)

 

PPFA- PN-L2 [Review available]

C26H28FeNP

C26H28FeNP_1

Aldrich (R,Sp)

Alfa (R,Sp) (S,Rp)

TCI (R,Sp) (S,Rp)

 

C25H26FeNP

C25H26FeNP

Alfa (R,Sp) (S,Rp)

 

C24H24FeNP

C24H24FeNP

Aldrich (S,Rp) (R,Sp)

Strem (S,Rp) (R,Sp)

 

P-S Ligand

FeSulPhos

C26H27FePS

C26H27FePS

Aldrich (Rp)

 

1,1′-P-P Ligands

CTH-JAFAPhos
C48H54FeN2O2P2 - [Review available]

C48H54FeN2O2P2_1

Alfa (Rp,Rp)

 

C38H37FeNP2

C38H37FeNP2

Aldrich (S,Rp) (R,Sp)

TCI (S,Rp) (R,Sp)

 

Mandyphos

C52H50FeN2P2 [Mandyphos- review available]

C52H50FeN2P2

Aldrich (S,S,Rp,Rp) (R,R,Sp,Sp)

Strem (R,R,Sp,Sp)

 

C52H74FeN2P2 [Mandyphos-2 review available]

C52H74FeN2P2

Aldrich (S,S,Rp,Rp) (R,R,Sp,Sp)

Strem (R,R,Sp,Sp)

 

C60H66FeN2P2 [Mandyphos-5 review available]

C60H66FeN2P2

Aldrich (S,S,Rp,Rp) (R,R,Sp,Sp)

Strem (S,S,Rp,Rp) (R,R,Sp,Sp)

 

C60H42F24FeN2P2 [Mandyphos-3 review available]

C60H42F24FeN2P2

Aldrich (S,S,Rp,Rp) (R,R,Sp,Sp)

Strem (R,R,Sp,Sp)

 

C64H74FeN2O4P2 [Mandyphos-4 review available]

C64H74FeN2O4P2

Aldrich (S,S,Rp,Rp) (R,R,Sp,Sp)

Strem (R,R,Sp,Sp)

 

Chenphos

C42H53Fe2NP[Chenphos review available]

C42H53Fe2NP2

Aldrich (S,Rp,Rphos) (R,Sp,Sphos)

Strem (S,Rp,Rphos) (R,Sp,Sphos)

 

Trifer

C50H54Fe3N2P[Trifer review available]

C50H54Fe3N2P2_1

Aldrich bis(S,Rp,Rphos) bis(R,Sp,Sphos)

Strem bis(S,Rp,Rphos) bis(R,Sp,Sphos)

 

Ferrocelane

C22H32FeP[Me-Ferrocelane] [Review available]

C22H32FeP2

Aldrich (R,R) (S,S)

Alfa (R,R) (S,S)

Strem (R,R) (S,S)

 

C26H40FeP2 [Et-Ferrocelane] [Review available]

C26H40FeP2

Aldrich (R,R) (S,S)

Alfa (R,R) (S,S)

Strem (R,R) (S,S)

 

FerroTANE

C24H36FeP[Et-FerroTANE] [Review available]

C24H36FeP2

Strem (R,R) (S,S)

 

C32H48BF4FeP2Rh [Rh-Et-FerroTANE] [Review available]

C32H48BF4FeP2Rha

Strem (S,S)

 

1,2-P-P Ligands

BoPhoz [Review available]

C37H35FeNP[BoPhoz]

C37H35FeNP2

Aldrich (S,Rp) (R,Sp)

Strem (S,Rp) (R,Sp)

 

Josiphos

C36H44FeP2 [Josiphos]

C36H44FeP2

Aldrich (S,Rp) (R,Sp)

Strem (S,Rp) (R,Sp)

 

C28H36FeO2P2 [Josiphos type]

C28H36FeO2P2

Aldrich (S,Rp) (R,Sp)

 

C32H40FeP2 [Josiphos type]

C32H40FeP2

Aldrich (S,Rp) (R,Sp)

Strem (S,Rp) (R,Sp)

 

C32H40FeP2 [Josiphos type]

C32H40FeP2_1

Aldrich (S,Rp) (R,Sp)

 

C32H52FeP2 [Josiphos type]

C32H52FeP2a

Aldrich (S,Rp) (R,Sp)

Strem (R,Sp)

 

C34H32FeO2P2 [Josiphos type]

C34H32FeO2P2

Aldrich (S,Rp) (R,Sp)

 

C34H38F6FeP2 [Josiphos type]

C34H38F6FeP2

Aldrich (S,Rp) (R,Sp)

Strem (R,Sp)

 

C34H44FeP2 [Josiphos type]

C34H44FeP2

Aldrich (S,Rp) (R,Sp)

 

C34H44FeP2 [Josiphos type]

C34H44FeP2_1

Aldrich (S,Rp) (R,Sp)

 

C36H36FeO2P2 [Josiphos type]

C36H36FeO2P2

Aldrich (R,Sp)

Strem (R,Sp)*

[*Suppliers stated configuration does correspond to structure given]

 

C36H44FeP2 [Josiphos type]

C36H44FeP2_1

Aldrich (S,Rp) (R,Sp)

Strem (S,Rp)(R,Sp)

[*Suppliers drawn structure does not correspond to configuration given]

 

 C36H56FeP2 [Josiphos type]

C36H56FeP2a

Aldrich (S,Rp) (R,Sp)

Strem (S,Rp) (R,Sp)

 

C38H52FeO2P2 [Josiphos type]

C38H52FeO2P2

Aldrich (S,Rp) (R,Sp)

 

C40H40FeP[Josiphos type]

C40H40FeP2

Aldrich (S,Rp) (R,Sp)

Strem (R,Sp)

 

C40H40F12FeP2 [Josiphos type]

C40H40F12FeP2

Aldrich (S,Rp) (R,Sp)

Strem (R,Sp)

 

C40H44FeP2 [Josiphos type]

C40H44FeP2

Aldrich (R,Sp)

 

C42H56FeO2P2 [Josiphos type]

C42H56FeO2P2

Aldrich (S,Rp) (R,Sp)

Strem (R,Sp)

 

C44H36F12FeP2 [Josiphos type]

C44H36F12FeP2_1

Aldrich (S,Rp) (R,Sp)

Strem (R,Sp)

 

C44H48FeO2P[Josiphos type]

C44H48FeO2P2

Aldrich (S,Rp) (R,Sp)

 

C46H52FeO2P2 [Josiphos type]

C46H52FeO2P2

Aldrich (S,Rp) (R,Sp)

 

C48H44FeP2 [Josiphos type]

C48H44FeP2

Aldrich (S,Rp) (R,Sp)

 

JoSPOphos

C26H36FeOP2 [JoSPOphos type]

C26H36FeOP2

Aldrich (S,Rp,Sphos) (R,Sp,Rphos)

Strem (S,Rp,Sphos(R,Sp,Rphos)

 

C28H32FeOP2 [JoSPOphos type]

C28H32FeOP2

Aldrich (S,Rp,Sphos) (R,Sp,Rphos)

Strem (S,Rp,Sphos) (R,Sp,Rphos)
Walphos

C42H36FeP2 [Walphos type]

C42H36FeP2_1

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

C42H48FeP2 [Walphos type]

C42H48FeP2 _1

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

C46H44FeP2 [Walphos type]

C46H44FeP2

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

C46H32F12FeP2 [Walphos type]

C46H32F12FeP2

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

C46H44F12FeP2 [Walphos type]

C46H44F12FeP2

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

C50H52FeP2 [Walphos type]

C50H52FeP2

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

C52H44F12FeO2P2 [Walphos type]

C52H44F12FeO2P2

Aldrich (S,Sp) (R,Rp)

Strem (R,Rp)

 

Taniaphos

C43H39FeNP[Taniaphos]

C43H39FeNP2_2

Aldrich (R,Rp) (S,Sp)

Strem (R,Rp)  (S,Sp)

 

C43H63FeNP2 [Taniaphos type]

C43H63FeNP2_2

Aldrich (R,Rp) (S,Sp)

Strem (R,Rp) (S,Sp)

 

1,2-P-P Catalysts

C32H52Cl2FeP2Pd

C32H52Cl2FeP2Pd_1

Aldrich (R,Sp)

Other

C5H5-DMAP

C45H36FeN2

C45H36FeN2

Strem (Rp)